河北大學

河北大學化學與環境科學學院研究生導師溫昕介紹如下：

 一、個人簡介

溫昕，男，河北安國人，理學博士，講師，2016年3月被引進到河北大學化學與環境科學學院工作，同年聘為碩士研究生導師。迄今為止發表學術論文20余篇，以第一作者在Chemical Communications, Dyes and Pigments及Industrial & Engineering Chemistry Research等國際知名期刊發表論文數篇，被

Synfacts等作為催化合成亮點工作進行推介。E-mail: wenxin767@163.com

二、研究方向

1. 多孔聚合物的設計、合成及應用;

2. 納米催化;

3. 綠色催化。

二、代表性論文

1. Yongqing Shi, Ru Yue, Yuangong Zhang, Shufang Lv, Libin Bai,* Chunfang Zhang, Xin Wen.* Cu powder/n-butylamine: An effective catalytic system for homo-and cross-coupling of terminal alkynes under ambient conditions. Catalysis Communications. 2019, DOI: 10.1016/j.catcom.2019.02.001.

2. Yuangong Zhang, Xin Wen,* Yongqing Shi, Ru Yue, Libin Bai, Qingtao Liu, and Xinwu Ba.* Sulfur-containing polymer as a platform for synthesis of size-controlled Pd nanoparticles for selective semihydrogenation of alkynes. Industrial & Engineering Chemistry Research 2019, 58(3), 1142-1149.

3. Yuangong Zhang, Bo Wang, Ye Zhang, Ying Zheng, Xin Wen,* Libin Bai, Yonggang Wu.* Hyperbranched glycopolymers of 2-(α-d-Mannopyranose) ethyl methacrylate and N,N’-methylenebisacrylamide: Synthesis, characterization and multivalent recognitions with Concanavalin A. Polymers, 2018, 10(2),

171.

4. Xin Wen, Huanhuan Zhang, Fei Tian, Xiaofang Liu, Libo Niu, Guoyi Bai.* Preparation of a H3PW12O40 deposited chitosan coated iron oxide magnetic core–shell nanocomposite for Friedel-Crafts Acylation. Journal of Nanoscience and Nanotechnology 2018, 18, 676–680.

5. Xin Wen, Xiaozhen Shi, Xianliang Qiao, Zhilei Wu, Guoyi Bai.* Ligand-free nickel-catalyzed semihydrogenation of alkynes with sodium borohydride: a highly efficient and selective process for cis-alkenes under ambient conditions. Chemical Communications 2017, 53, 5372-5375.

6. Xin Wen, Dongxin Zhang, Tianci Ren, Jinchong Xiao, Yonggang Wu, Libin Bai,* Xinwu Ba.* Yellow emitting materials: Truxene-based conjugated hyperbranched polymer containing difluoroboron-diketonate complexes. Dyes and Pigments 2017, 137, 437-444.

7. Xianliang Qiao, Libo Niu, Huiling Zhang, Xin Wen, Yingying Cao, Guoyi Bai.* Controllable fabrication of a novel porous Ni-alginate hybrid material for hydrogenation. Applied Catalysis B: Environmental, 2017, 218, 721-730.

8. Yingying Cao, Libo Niu, Xin Wen, Wenhui Feng, Li Huo, Guoyi Bai.* Novel layered double hydroxide/oxide-coated nickel-based core–shell nanocomposites for benzonitrile selective hydrogenation: An interesting water switch. Journal of Catalysis, 2016, 339, 9-13.

9. Xin Wen, Xianliang Qiao, Xue Han, Libo Niu, Li Huo, Guoyi Bai.* Multifunctional magnetic branched polyethylenimine nanogels with in-situ generated Fe3O4 and their applications as dye adsorbent and catalyst support. Journal of Materials Science 2016, 51(6), 3170-3181.

10. Xin Wen, Yingying Cao, Xianliang Qiao, Libo Niu, Li Huo, Guoyi Bai.* Significant effect of base on the improvement of selectivity in the hydrogenation of benzoic acid over NiZrB amorphous alloy supported on γ-Al2O3. Catalysis Science & Technology 2015, 5(6), 3281–3287.

11. Xin Wen, Guang Li, Qingzhi Chen, Hailei Zhang, Xinwu Ba, Guoyi Bai.* Organic- soluble palladium nanoparticles costabilized by hyperbranched polymer and dispersants as highly efficient and reusable catalysts in biphasic solution. Industrial & Engineering Chemistry Research 2014, 53, 11646–

11652.

12. Guoyi Bai,* Xin Wen, Zhen Zhao, Fei Li, Huixian Dong, Mande Qiu. Chemoselective hydrogenation of benzoic acid over Ni−Zr−B−PEG(800) nanoscale amorphous alloy in water. Industrial & Engineering Chemistry Research 2013, 52, 2266−2272.

13. Xin Wen, Zhen Zhao, Yingying Cao, Huixian Dong, Chen Liu, Hailong Chu, Guoyi Bai.* Selective hydrogenation of ethyl benzoate over Ni–B amorphous alloys supported on γ-Al2O3. Research on Chemical Intermediates 2015, 41, 6351–6361.

三、主持和參與的基金項目

1. 國家自然科學基金項目：pH刺激響應“蛋黃-蛋殼”型介孔納米反應器的構筑及其對苯甲醇選擇性氧化反應的調控， 25萬，2018—2020年，主持人;

2. 河北大學引進人才啟動經費：鎳基催化劑的炔選擇性加氫性能研究，8萬，2016—2020年，主持人;

3. 河北省自然科學基金項目：pH響應性聚合物修飾的Pd基yolk-shell型納米反應器及其可控催化特性 ，4萬，2016—2018年，主持人;

4. 河北省高等學校科學技術研究基金項目：基于功能超支化聚乙烯亞胺構筑鈀基納米催化劑及其加氫性能，4萬，2014—2016年，主持人;

5. 國家自然科學基金項目：核殼結構鎳基納米催化劑對多不飽和官能團化合物“非常規”選擇性加氫反應的調控，82萬，2013—2017年，第二完成人。