武漢理工大學材料科學與工程學院研究生導師：向萬春

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一、姓名：向萬春

二、基本情況：

1、出生年月：1983.1

2、學位：博士

3、職稱：副研究員

4、工作院系：硅酸鹽建筑材料國家重點實驗室

三、教育經歷(從大學開始)：

2001-2005：陜西師范大學，理學學士

2005-2010：中國科學院化學研究所，理學博士

四、工作經歷：

2010-2011：中國科學院西安光學精密機械研究所，助理研究員

2011-2014：澳大利亞莫納什大學博士后

五、研究領域(不多于3個)：

染料敏化太陽能電池

太陽能的有效利用是解決化石能源的日益枯竭及溫室效應和環境污染等問題的重要途徑之一。太陽能電池能實現無機械轉化和污染副產品的情況下，把太陽能直接轉化為電能，一直是研究熱點。染料敏化太陽能電池由于其價格便宜、工藝簡單、環境友好、形狀多樣化等優點而可能替代傳統的硅基電池。染料敏化太陽能電池通常由在導電基底上的敏化納晶多孔半導體作為工作電極，由鉑等作為對電極，在兩片電極中間由含有氧化還原電對的電解質構成。氧化還原電對在兩片電極之間傳輸電子，同時在電子注入到半導體能帶后使激發態染料得以再生。近年，腐蝕性低，吸光弱的基于聯吡啶鈷的電解質使得電解質的發展逐漸轉向無碘電解質。我們已經成功將過渡金屬(鈷、錳等)配合物氧化還原電對用于染料敏化太陽能電池中并取得了優異的光電轉換效率。通過對電解質進行凝膠固化，器件的穩定性得到了很大的提升。同時，我們采用水作為電解質溶劑來代替有毒的有機溶劑，獲得了目前世界效率最高的水電解質染料敏化太陽能電池，這是制備環境友好的太陽能電池器件的一個重要途徑。研究成果分別發表在能源與化學頂級期刊Energy & Environ. Sci.，Angew. Chem. In. Ed.，ChemSusChem等并被選為封面文章和熱點文章進行報道。

鈣鈦礦太陽能電池

有機無機雜化鈣鈦礦太陽能電池自2012年起已在世界范圍內進行廣泛的研究，并被科學雜志選為2013年科學界十大突破之一。在這種新型全固態雜化太陽能電池中，具有ABX3晶型結構的有機-無機-鹵素鈣鈦礦材料為吸光材料。A是有機陽離子，B是金屬離子，X是鹵素離子。這種三鹵鈣鈦礦材料具有很寬的吸光范圍(300-800 nm)和高摩爾吸光系數，因此，很薄的一層吸光層(~ 300 nm)就足以滿足高效鈣鈦礦太陽能電池的要求。而提高鈣鈦礦太陽能電池光電轉換效率和穩定性的方法在于材料的選擇和工藝的優化。這種低成本和簡單工藝的太陽能電池是光伏建筑一體化工程的重要組成部分。

六、科研項目(不多于5項)：

水電解質pH值的調控及其對p型染料敏化太陽能電池光電性能的影響和機理研究,國家自然科學基金，25萬，2016年1月-2018年12月，項目負責人

乙二胺鈷水電解質在p-型染料敏化太陽能電池中的應用，武漢理工大學自主創新研究基金，5萬，2015年1月-2016年12月，項目負責人

TiO2基粉體的制備、成形及其在光電領域的應用，硅酸鹽建筑材料國家重點實驗室自主研究課題，15萬，2015年1月-2015年12月，項目負責人

七、代表性論文及著作(不多于10項)：

1. Wanchun Xiang, Fuzhi Huang,Yi-Bing Cheng, Udo Bach and Leone Spiccia, Energy Environ. Sci., 2013, 6,121-127. (封面文章和熱點文章)

2. Wanchun Xiang, Akhil Gupta,Muhammad Kalim Kashif, Ante Bilic,Richard A. Evans, Leone Spicciaand Udo Bach, ChemSusChem, 2013, 6,256-260.

3. Wanchun Xiang, WenchaoHuang, Udo Bach and Leone Spiccia, Chem. Commun.,2013, 49, 8997-8999.

4. Wanchun Xiang,Yanyan Fang, Shibi Fang, Yuan Lin, Electrochimica Acta, 2011,56,1605-1610.

5. Wanchun Xiang,Dehong Chen, Rachel A. Caruso, Yibing Cheng, Udo Bach and Leone Spiccia, ChemSusChem,2015, 8, 3704- 3711.

6. Cunku Dong, Wanchun Xiang,Fuzhi Huang, Dongchuan Fu, Udo Bach, Yi-Bing Cheng, Xin Li and Leone Spiccia, Angew.Chem. Int. Ed., 2014, 53, 6933-6937

7. Cunku Dong, Wanchun Xiang, Fuzhi Huang, Dongchuan Fu, Wenchao Huang, Udo Bach,Yi-Bing Cheng Leone Spiccia and Xin Li, Nanoscale, 2014, 6, 3704-3711.

8. YangChen, Fuzhi Huang, Wanchun Xiang,Dehong Chen, Lu Cao, Leone Spiccia, Rachel A. Caruso and Yi-Bing Cheng,Nanoscale,, 2014, 6, 13787–13794

9. Jeremiah Toster, K. Swaminathan Iyer, Wanchun Xiang, Federico Rosei, Leone Spiccia and Colin L. Raston, Nanoscale,2013, 5, 873-876.

10. Yujian Huang, Wanchun Xiang, Xiaowen Zhou, Yuan Lin, Shibi Fang, Electrochimica Acta, 2013, 89, 29-34.

八、聯系方式：

1、E-mail：xiangwanchun@whut.edu.cn

2、工作地址(實驗室)：武漢理工大學東院硅酸鹽建筑材料國家重點實驗室南樓600室

二、 Name：Wanchun Xiang

二、Brief introduction：

1、Date of Birth： 1983.1

2、Degree：PhD

3、Title：Associate Professor

4、Working department：State Key Laboratory of Silicate Materials for Architectures

三、Education experience ：

B.S. in Chemistry, Shaanxi Normal University, China, 2005

PhD in Chemistry, Institute of Chemistry, Chinese Academy of Sciences, China, 2010

四、Working ecperience：

2010-2011：Xi’An Institute of Optics and Precision Mechanics, Chinese Academy of Sciences,China, Assistant Professor

2011-2014：Monash University, Australia, Research Fellow

五、Research field (no more than 3)

Due to the gradual depletion of fossil fuels and the increasing energy demand to support the current model of economic growth,mankind is facing a global energy problem. Amongst the number of alternative resources, renewable energies are rapidly becoming the leading solution to fulfill the growing needs of power sources. At present, solar energy is considered the most promising renewable resource. A simple calculation leads self-evidently to the conclusion that covering only around 0.1% of the earth’s surface by means of energy conversion devices having an efficiency of about 10% would satisfy the present global energy needs. These encouraging numbers are inducing the scientific community to make even greater efforts towards the direction of improving solar energy conversion technologies as well as proposing new intriguing solutions.

Dye-sensitized solar cells

Dye-sensitized solar cells (DSCs) have been intensely studied as promising renewable energy technology with the potential to achieve high energy conversion efficiencies at low cost. DSCs typically consist of a sensitized mesoporous semiconductor film on a conductive substrate as working electrode and a platinized counter electrode, bridged by an electrolyte film containing the reduced and oxidized forms of the redox mediator. The latter mediates charge transport between the two electrodes and is also responsible for the regeneration of the photooxidized dye, following electron injection into the TiO2. The application of a cobalt(II)/(III) tris(bipyridine) based electrolyte has recently resulted in a benchmark efficiency of >12%. This result has accelerated the transition to non-iodide based electrolytes, which are less corrosive and exhibit weaker absorption of visible light. Transition metal, such as cobalt, iron and manganese based redox couple have been successfully developed and promising efficiencies were obtained in both n-type and p-type DSCs. By solidifying the electrolyte, the stability of the devices can be further improved. More mportantly, the replacement of organic solvent in the electrolyte with water paves the way for environmentally friendly devices, which keeps us in the leading role in this area worldwide. These breakthroughs were published on Energy & Environ.Sci. and Angew. Chem. In. Ed., and one of them was selected as the front-cover and hot article.

Perovskite solar cells

Alkylammonium lead(II) halides ([CH3NH3PbX3]n) have been shown to be efficient photovoltaic materials with excellent light harvesting, high carrier mobility, and facile solution processability. A rapid growth of intensive research into this photovoltaic technology since 2012 has resulted in a certified energy conversion efficiency over 20% and the topic has been selected as one of the top 10 breakthroughs of 2013 as announced by the journal Science.These organic– inorganic lead(II) complexes crystallize in the well-known perovskite structure with general formula ABX3, where A is an organic cation, Bis a metal, and X is a halide. A very thin perovskite film (~ 300 nm) is sufficient enough for highly-performed perovskite solar cell due to its broad light absorption range from 300 to 800 nm and a high molar extinction coefficient. Materials selection and process optimization are essential to high performance of perovskite solar cells with long-term stability. This new type of solar cells with low cost and easy fabrication is the key part of the building integrated photovoltaics (BIPV).

六、Research project(no more than 5)

The effect of pH on the performance of p-type dye-sensitized solar cells. National Science Fund of China, 0.25 million. Jan. 2016- Dec. 2018. Project Leader

The application of cobalt ethylenediamine into p-type dye-sensitized solar cells. 5,0000 CNY, Wuhan University of Technology, Jan. 2015-Dec. 2016. Project Leader

The preparation, formation and application of TiO2-based particles. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Jan.2015- Dec. 2015, Project Leader

七、Representative papers and works

1. Wanchun Xiang, Fuzhi Huang,Yi-Bing Cheng, Udo Bach and Leone Spiccia, Energy Environ. Sci., 2013, 6,121-127. (front cover and hot article)

2. Wanchun Xiang, Akhil Gupta,Muhammad Kalim Kashif, Ante Bilic,Richard A. Evans, Leone Spicciaand Udo Bach, ChemSusChem, 2013, 6,256-260.

3. Wanchun Xiang, Wenchao Huang, Udo Bach and Leone Spiccia, Chem. Commun.,2013, 49, 8997-8999.

4. Wanchun Xiang, Yanyan Fang, Shibi Fang, Yuan Lin, Electrochimica Acta,2011,56,1605-1610.

5. Wanchun Xiang, Dehong Chen, Rachel A. Caruso, Yibing Cheng, Udo Bach and Leone Spiccia, ChemSusChem, 2015, 8, 3704- 3711.

6. Cunku Dong, Wanchun Xiang, Fuzhi Huang, Dongchuan Fu, Udo Bach, Yi-Bing Cheng, Xin Li and Leone Spiccia, Angew. Chem. Int. Ed.,2014, 53, 6933-6937

7. Cunku Dong, Wanchun Xiang, Fuzhi Huang, Dongchuan Fu, Wenchao Huang, Udo Bach, Yi-Bing Cheng Leone Spiccia and Xin Li, Nanoscale, 2014, 6, 3704-3711.

8. Yang Chen, Fuzhi Huang, Wanchun Xiang, Dehong Chen, Lu Cao, Leone Spiccia, Rachel A. Caruso and Yi-Bing Cheng,Nanoscale,, 2014, 6, 13787–13794

9. Jeremiah Toster, K. Swaminathan Iyer, Wanchun Xiang, Federico Rosei, Leone Spiccia and Colin L. Raston,Nanoscale, 2013, 5, 873-876.

10. Yujian Huang, Wanchun Xiang, Xiaowen Zhou, Yuan Lin,Shibi Fang, Electrochimica Acta, 2013, 89, 29-34.

八、Contact information ：

1、E-mail：xiangwanchun@whut.edu.cn

2、Office:Room 600, South Building, State Key Laboratory of Silicate Materials for Architectures Wuhan University of Technology No.122 Luoshi Rd, Wuhan, China